There is a disagreement among poskim as to how libun kal works. The Pri Migadim (Mishbetzos Zahav 452:4) writes that it expels the issur from the utensil. Accordingly, it is questionable if one can kasher with libun kal without first waiting 24 hours. However, the Shulchan Aruch Harav (451:10) writes that libun kal consumes the absorbed flavor. According to Shulchan Aruch Harav, one can kasher with libun kal without waiting 24 hours. Rav Schachter, Shlita ruled in accordance with the Shulchan Aruch Harav, and if one kashers with libun kal, there is no requirement to wait 24 hours.
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